IndiumV3, Main, Repository, bibRecord, 001699

Photochemical Grafting and Patterning of Organic Monolayers on Indium Tin Oxide Substrates

Identifieur interne : 001699 ( Main/Repository ); précédent : 001698; suivant : 001700

Photochemical Grafting and Patterning of Organic Monolayers on Indium Tin Oxide Substrates

Auteurs : RBID : Pascal:12-0200356

Descripteurs français

Pascal (Inist)
- Greffage, Formation motif, Couche monomoléculaire, Oxyde d'indium, Oxyde d'étain, Substrat, Alcène, Modification, Eau, Angle contact, Spectrométrie photoélectron, Rayon X, Microscopie force atomique, Hydrophobicité, Réaction one pot, Déprotection, Interface, Réaction chimique, Température ambiante, Dispositif.
Wicri :
- concept : Eau.

English descriptors

KwdEn :
- Alkene, Atomic force microscopy, Chemical reaction, Contact angle, Deprotection, Device, Grafting, Hydrophobicity, Indium oxide, Interface, Modification, Monolayer, One pot reaction, Patterning, Photoelectron spectrometry, Room temperature, Substrate, Tin oxide, Water, X ray.

Abstract

Covalently attached organic layers on indium tin oxide (ITO) surfaces were prepared by the photochemical grafting with l-alkenes. The surface modification was monitored with static water contact angle, X-ray photoelectron spectroscopy (XPS), and atomic force microscopy (AFM) measurements. Hydrophobic methyl-terminated ITO surfaces can be obtained via the grafting of tetradec-1-ene, whereas the attachment of ω-functionalized I-alkenes leads to functionalized ITO surfaces. The use of a C≡C-Ge(CH₃)₃ terminus allows for facile tagging of the surface with an azido group via a one-pot deprotection/click reaction, resulting in bio/electronically active interfaces. The combination of nonaggressive chemicals (alkenes), mild reaction conditions (room temperature), and a light-induced grafting that facilitates the direct patterning of organic layers makes this simple approach highly promising for the development of ITO-based (bio)electronic devices.

Links toward previous steps (curation, corpus...)

to stream Main, to step Corpus: 001E43

Links to Exploration step

Pascal:12-0200356

Le document en format XML

<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Photochemical Grafting and Patterning of Organic Monolayers on Indium Tin Oxide Substrates</title>
<author><name>YAN LI</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Laboratory of Organic Chemistry, Wageningen University, Dreijenplein 8</s1>
<s2>6703 HB Wageningen</s2>
<s3>NLD</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
</inist:fA14>
<country>Pays-Bas</country>
<wicri:noRegion>6703 HB Wageningen</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Znithof, Han" uniqKey="Znithof H">Han Znithof</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Laboratory of Organic Chemistry, Wageningen University, Dreijenplein 8</s1>
<s2>6703 HB Wageningen</s2>
<s3>NLD</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
</inist:fA14>
<country>Pays-Bas</country>
<wicri:noRegion>6703 HB Wageningen</wicri:noRegion>
</affiliation>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Department of Chemical and Materials Engineering, King Abdulaziz University</s1>
<s2>Jeddah</s2>
<s3>SAU</s3>
<sZ>2 aut.</sZ>
</inist:fA14>
<country>Arabie saoudite</country>
<wicri:noRegion>Jeddah</wicri:noRegion>
</affiliation>
</author>
</titleStmt>
<publicationStmt><idno type="inist">12-0200356</idno>
<date when="2012">2012</date>
<idno type="stanalyst">PASCAL 12-0200356 INIST</idno>
<idno type="RBID">Pascal:12-0200356</idno>
<idno type="wicri:Area/Main/Corpus">001E43</idno>
<idno type="wicri:Area/Main/Repository">001699</idno>
</publicationStmt>
<seriesStmt><idno type="ISSN">0743-7463</idno>
<title level="j" type="abbreviated">Langmuir</title>
<title level="j" type="main">Langmuir</title>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Alkene</term>
<term>Atomic force microscopy</term>
<term>Chemical reaction</term>
<term>Contact angle</term>
<term>Deprotection</term>
<term>Device</term>
<term>Grafting</term>
<term>Hydrophobicity</term>
<term>Indium oxide</term>
<term>Interface</term>
<term>Modification</term>
<term>Monolayer</term>
<term>One pot reaction</term>
<term>Patterning</term>
<term>Photoelectron spectrometry</term>
<term>Room temperature</term>
<term>Substrate</term>
<term>Tin oxide</term>
<term>Water</term>
<term>X ray</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Greffage</term>
<term>Formation motif</term>
<term>Couche monomoléculaire</term>
<term>Oxyde d'indium</term>
<term>Oxyde d'étain</term>
<term>Substrat</term>
<term>Alcène</term>
<term>Modification</term>
<term>Eau</term>
<term>Angle contact</term>
<term>Spectrométrie photoélectron</term>
<term>Rayon X</term>
<term>Microscopie force atomique</term>
<term>Hydrophobicité</term>
<term>Réaction one pot</term>
<term>Déprotection</term>
<term>Interface</term>
<term>Réaction chimique</term>
<term>Température ambiante</term>
<term>Dispositif</term>
</keywords>
<keywords scheme="Wicri" type="concept" xml:lang="fr"><term>Eau</term>
</keywords>
</textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">Covalently attached organic layers on indium tin oxide (ITO) surfaces were prepared by the photochemical grafting with l-alkenes. The surface modification was monitored with static water contact angle, X-ray photoelectron spectroscopy (XPS), and atomic force microscopy (AFM) measurements. Hydrophobic methyl-terminated ITO surfaces can be obtained via the grafting of tetradec-1-ene, whereas the attachment of ω-functionalized I-alkenes leads to functionalized ITO surfaces. The use of a C≡C-Ge(CH<sub>3</sub>
)<sub>3</sub>
 terminus allows for facile tagging of the surface with an azido group via a one-pot deprotection/click reaction, resulting in bio/electronically active interfaces. The combination of nonaggressive chemicals (alkenes), mild reaction conditions (room temperature), and a light-induced grafting that facilitates the direct patterning of organic layers makes this simple approach highly promising for the development of ITO-based (bio)electronic devices.</div>
</front>
</TEI>
<inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>0743-7463</s0>
</fA01>
<fA02 i1="01"><s0>LANGD5</s0>
</fA02>
<fA03 i2="1"><s0>Langmuir</s0>
</fA03>
<fA05><s2>28</s2>
</fA05>
<fA06><s2>12</s2>
</fA06>
<fA08 i1="01" i2="1" l="ENG"><s1>Photochemical Grafting and Patterning of Organic Monolayers on Indium Tin Oxide Substrates</s1>
</fA08>
<fA11 i1="01" i2="1"><s1>YAN LI</s1>
</fA11>
<fA11 i1="02" i2="1"><s1>ZNITHOF (Han)</s1>
</fA11>
<fA14 i1="01"><s1>Laboratory of Organic Chemistry, Wageningen University, Dreijenplein 8</s1>
<s2>6703 HB Wageningen</s2>
<s3>NLD</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
</fA14>
<fA14 i1="02"><s1>Department of Chemical and Materials Engineering, King Abdulaziz University</s1>
<s2>Jeddah</s2>
<s3>SAU</s3>
<sZ>2 aut.</sZ>
</fA14>
<fA20><s1>5350-5359</s1>
</fA20>
<fA21><s1>2012</s1>
</fA21>
<fA23 i1="01"><s0>ENG</s0>
</fA23>
<fA43 i1="01"><s1>INIST</s1>
<s2>20642</s2>
<s5>354000509641970050</s5>
</fA43>
<fA44><s0>0000</s0>
<s1>© 2012 INIST-CNRS. All rights reserved.</s1>
</fA44>
<fA45><s0>57 ref.</s0>
</fA45>
<fA47 i1="01" i2="1"><s0>12-0200356</s0>
</fA47>
<fA60><s1>P</s1>
</fA60>
<fA61><s0>A</s0>
</fA61>
<fA64 i1="01" i2="1"><s0>Langmuir</s0>
</fA64>
<fA66 i1="01"><s0>USA</s0>
</fA66>
<fC01 i1="01" l="ENG"><s0>Covalently attached organic layers on indium tin oxide (ITO) surfaces were prepared by the photochemical grafting with l-alkenes. The surface modification was monitored with static water contact angle, X-ray photoelectron spectroscopy (XPS), and atomic force microscopy (AFM) measurements. Hydrophobic methyl-terminated ITO surfaces can be obtained via the grafting of tetradec-1-ene, whereas the attachment of ω-functionalized I-alkenes leads to functionalized ITO surfaces. The use of a C≡C-Ge(CH<sub>3</sub>
)<sub>3</sub>
 terminus allows for facile tagging of the surface with an azido group via a one-pot deprotection/click reaction, resulting in bio/electronically active interfaces. The combination of nonaggressive chemicals (alkenes), mild reaction conditions (room temperature), and a light-induced grafting that facilitates the direct patterning of organic layers makes this simple approach highly promising for the development of ITO-based (bio)electronic devices.</s0>
</fC01>
<fC02 i1="01" i2="X"><s0>001C01</s0>
</fC02>
<fC02 i1="02" i2="X"><s0>001C01I03</s0>
</fC02>
<fC03 i1="01" i2="X" l="FRE"><s0>Greffage</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="ENG"><s0>Grafting</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="SPA"><s0>Injerto</s0>
<s5>01</s5>
</fC03>
<fC03 i1="02" i2="X" l="FRE"><s0>Formation motif</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="ENG"><s0>Patterning</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="SPA"><s0>Formacíon motivo</s0>
<s5>02</s5>
</fC03>
<fC03 i1="03" i2="X" l="FRE"><s0>Couche monomoléculaire</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="ENG"><s0>Monolayer</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="SPA"><s0>Capa monomolecular</s0>
<s5>03</s5>
</fC03>
<fC03 i1="04" i2="X" l="FRE"><s0>Oxyde d'indium</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="ENG"><s0>Indium oxide</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="SPA"><s0>Indio óxido</s0>
<s5>04</s5>
</fC03>
<fC03 i1="05" i2="X" l="FRE"><s0>Oxyde d'étain</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="ENG"><s0>Tin oxide</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="SPA"><s0>Estaño óxido</s0>
<s5>05</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE"><s0>Substrat</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="ENG"><s0>Substrate</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="SPA"><s0>Substrato</s0>
<s5>06</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE"><s0>Alcène</s0>
<s2>NK</s2>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="ENG"><s0>Alkene</s0>
<s2>NK</s2>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA"><s0>Alqueno</s0>
<s2>NK</s2>
<s5>07</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE"><s0>Modification</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG"><s0>Modification</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA"><s0>Modificación</s0>
<s5>08</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE"><s0>Eau</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG"><s0>Water</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA"><s0>Agua</s0>
<s5>09</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE"><s0>Angle contact</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG"><s0>Contact angle</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA"><s0>Angulo contacto</s0>
<s5>10</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE"><s0>Spectrométrie photoélectron</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="ENG"><s0>Photoelectron spectrometry</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA"><s0>Espectrometría fotoelectrón</s0>
<s5>11</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE"><s0>Rayon X</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="X" l="ENG"><s0>X ray</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA"><s0>Rayos X</s0>
<s5>12</s5>
</fC03>
<fC03 i1="13" i2="X" l="FRE"><s0>Microscopie force atomique</s0>
<s5>13</s5>
</fC03>
<fC03 i1="13" i2="X" l="ENG"><s0>Atomic force microscopy</s0>
<s5>13</s5>
</fC03>
<fC03 i1="13" i2="X" l="SPA"><s0>Microscopía fuerza atómica</s0>
<s5>13</s5>
</fC03>
<fC03 i1="14" i2="X" l="FRE"><s0>Hydrophobicité</s0>
<s5>14</s5>
</fC03>
<fC03 i1="14" i2="X" l="ENG"><s0>Hydrophobicity</s0>
<s5>14</s5>
</fC03>
<fC03 i1="14" i2="X" l="SPA"><s0>Hidrofobicidad</s0>
<s5>14</s5>
</fC03>
<fC03 i1="15" i2="X" l="FRE"><s0>Réaction one pot</s0>
<s5>15</s5>
</fC03>
<fC03 i1="15" i2="X" l="ENG"><s0>One pot reaction</s0>
<s5>15</s5>
</fC03>
<fC03 i1="15" i2="X" l="SPA"><s0>Reacción one pot</s0>
<s5>15</s5>
</fC03>
<fC03 i1="16" i2="X" l="FRE"><s0>Déprotection</s0>
<s5>16</s5>
</fC03>
<fC03 i1="16" i2="X" l="ENG"><s0>Deprotection</s0>
<s5>16</s5>
</fC03>
<fC03 i1="16" i2="X" l="SPA"><s0>Desprotección</s0>
<s5>16</s5>
</fC03>
<fC03 i1="17" i2="X" l="FRE"><s0>Interface</s0>
<s5>17</s5>
</fC03>
<fC03 i1="17" i2="X" l="ENG"><s0>Interface</s0>
<s5>17</s5>
</fC03>
<fC03 i1="17" i2="X" l="SPA"><s0>Interfase</s0>
<s5>17</s5>
</fC03>
<fC03 i1="18" i2="X" l="FRE"><s0>Réaction chimique</s0>
<s5>18</s5>
</fC03>
<fC03 i1="18" i2="X" l="ENG"><s0>Chemical reaction</s0>
<s5>18</s5>
</fC03>
<fC03 i1="18" i2="X" l="SPA"><s0>Reacción química</s0>
<s5>18</s5>
</fC03>
<fC03 i1="19" i2="X" l="FRE"><s0>Température ambiante</s0>
<s5>19</s5>
</fC03>
<fC03 i1="19" i2="X" l="ENG"><s0>Room temperature</s0>
<s5>19</s5>
</fC03>
<fC03 i1="19" i2="X" l="SPA"><s0>Temperatura ambiente</s0>
<s5>19</s5>
</fC03>
<fC03 i1="20" i2="X" l="FRE"><s0>Dispositif</s0>
<s5>20</s5>
</fC03>
<fC03 i1="20" i2="X" l="ENG"><s0>Device</s0>
<s5>20</s5>
</fC03>
<fC03 i1="20" i2="X" l="SPA"><s0>Dispositivo</s0>
<s5>20</s5>
</fC03>
<fC07 i1="01" i2="X" l="FRE"><s0>Hydrocarbure</s0>
<s2>FX</s2>
<s5>21</s5>
</fC07>
<fC07 i1="01" i2="X" l="ENG"><s0>Hydrocarbon</s0>
<s2>FX</s2>
<s5>21</s5>
</fC07>
<fC07 i1="01" i2="X" l="SPA"><s0>Hidrocarburo</s0>
<s2>FX</s2>
<s5>21</s5>
</fC07>
<fC07 i1="02" i2="X" l="FRE"><s0>Composé éthylénique</s0>
<s5>22</s5>
</fC07>
<fC07 i1="02" i2="X" l="ENG"><s0>Ethylenic compound</s0>
<s5>22</s5>
</fC07>
<fC07 i1="02" i2="X" l="SPA"><s0>Compuesto etilénico</s0>
<s5>22</s5>
</fC07>
<fN21><s1>156</s1>
</fN21>
<fN44 i1="01"><s1>OTO</s1>
</fN44>
<fN82><s1>OTO</s1>
</fN82>
</pA>
</standard>
</inist>
</record>

Pour manipuler ce document sous Unix (Dilib)

EXPLOR_STEP=IndiumV3/Data/Main/Repository

HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 001699 | SxmlIndent | more

HfdSelect -h $EXPLOR_AREA/Data/Main/Repository/biblio.hfd -nk 001699 | SxmlIndent | more

Pour mettre un lien sur cette page dans le réseau Wicri

{{Explor lien
   |wiki=   *** parameter Area/wikiCode missing *** 
   |area=    IndiumV3
   |flux=    Main
   |étape=   Repository
   |type=    RBID
   |clé=     Pascal:12-0200356
   |texte=   Photochemical Grafting and Patterning of Organic Monolayers on Indium Tin Oxide Substrates
}}

This area was generated with Dilib version V0.5.77.
Data generation: Mon Jun 9 10:27:54 2014. Site generation: Thu Mar 7 16:19:59 2024

	Serveur d'exploration sur l'Indium
	Attention, ce site est en cours de développement ! Attention, site généré par des moyens informatiques à partir de corpus bruts. Les informations ne sont donc pas validées.

Serveur d'exploration sur l'Indium

Photochemical Grafting and Patterning of Organic Monolayers on Indium Tin Oxide Substrates

Photochemical Grafting and Patterning of Organic Monolayers on Indium Tin Oxide Substrates

Descripteurs français

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri